No, AFAIK there are no plans for an A330 right now. On the "Ultimate" product line, FF will have to finish the A320, and although the beta is more than impressive, I guess it will take them up to one year before they have achieved full maturity and feature completeness. If at all, my guess would then be for an A320 derivate, either the A321, or something about engine options (the A320U runs exclusively with the CFM-56).
On their "Pro" product line, I guess FF has to do something about their A350 (customers being quite annoyed meanwhile as the promised upgrade from Advanced to Pro never came - and now QPAC officially announced the end of their engagement in X-Plane development). And somebody let slip they're working on a new Boing. As they cover already the B757, B767 and B777, speculations are either a refurbished B777, or with some luck & hope a B744 (the only model without any decent coverage on XP, given the default one is quite a poor representation, and PMDG having just clarified they won't port their Queen II to XP). The 737 is fairly well covered, with IXEG taking care of the classic, and EADT offering a marvelous freeware NG family (at least the 737-800 and 737-700). Theoretically, there would be room for a MAX, but availability of performance data for this aircraft is even thinner than for A320 NEOs, so I guess it will take some time before we see one of them simulated properly.